4.7 Article

Streamlined approach to a new gelator: inspiration from solid-state interactions for a mercury-induced gelation

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 20, Pages 3511-3513

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c002081h

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Funding

  1. Arnold and Mabel Beckman Foundation
  2. 3M
  3. University of Michigan

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A new gelator was discovered by identifying molecular scaffolds exhibiting 1D intermolecular interactions in the solid-state and synthesizing derivatives. Gelation can be triggered by adding Hg(OAc)(2) to a precursor molecule. The in situ gelation is selective for Hg(2+) over other metals.

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