Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 31, Pages 5781-5783Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01292k
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Funding
- NIH [RO1 DK076084]
- HHMI
- Department of Education
- NATIONAL INSTITUTE OF DIABETES AND DIGESTIVE AND KIDNEY DISEASES [R01DK076084] Funding Source: NIH RePORTER
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A unique method has been developed for the formation of multivalent cyclic peptides. This procedure exploits on-resin peptide cyclization using a photoinitiated thiol-ene click reaction and subsequent clustering using thiol-yne photochemistry. Both reactions utilize the sulfhydryl group on natural cysteine amino acids to participate in the thiol-mediated reactions.
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