4.7 Article

Multistep electron transfer systems based on silicon phthalocyanine, [60]fullerene and trinitrofluorenone

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 22, Pages 3944-3946

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c002077j

Keywords

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Funding

  1. Spanish Ministry of Science and Innovation
  2. European FEDER
  3. Generalitat Valenciana [CTQ2007-67888/BQU, CTQ2008-05901/BQU, CONSOLIDER-INGENIO CSD2007-00007, ACOMP/2009/039, ACOMP/2009/056]
  4. Ministry of Education, Culture, Sports, Science and Technology, Japan [21750146]
  5. KOSEF/MEST [R31-2008-000-10010-0]

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The synthesis and photodynamics in the absence and in the presence of Mg(2+) ions of a novel TNF-C(60)-SiPc-C(60)-TNF pentad are reported. The redox gradient approach allows to obtain a long-lived CS state of 160 ns and 200 mu s in the absence and in the presence of Mg(2+) ions, respectively.

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