4.7 Article

Metal-free reductions of N-heterocycles via Lewis acid catalyzed hydrogenation

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 27, Pages 4884-4886

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00719f

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Funding

  1. NSERC of Canada
  2. Killam Research Fellowship
  3. Canada Research Chair
  4. NSERC-PGS-D

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N-Heterocycles form weak adducts with B(C6F5)(3) that exist in equilibrium with the corresponding FLP; nonetheless, these heterocycles are reduced in the presence of a catalytic amount of the borane B(C6F5)(3) and H-2.

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