Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 4, Pages 371-384Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b812466c
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- KRF [2007-357-C00057]
- Global COE (Center of Excellence) program in Osaka University
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Skeletal reorganization of enynes was studied by electrophilic activation of alkynes with various metal catalysts; the products obtained can be classified into two types, one involving carbon-carbon bond single cleavage (type I) and the other involving carbon-carbon bond double cleavage (type II). Summarized in this review are our studies of the catalytic skeletal reorganization of enynes through the electrophilic activation of alkynes, and recent results from selective formation of type II products.
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