4.7 Article

Stereoselective and controlled polymerization of D,L-lactide using indium(III) trichloride

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 19, Pages 2736-2737

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b902968k

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Indium trichloride, benzyl alcohol, and triethylamine (without an added 'directing' multidentate ligand) generate a catalyst in situ for the room temperature polymerization of D, L-lactide affording highly heterotactic polylactide of controlled molecular weight and narrow molecular weight distribution.

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