4.7 Article

Green molecular transformation by a B-12-TiO2 hybrid catalyst as an alternative to tributyltin hydride

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 42, Pages 6427-6429

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b913255d

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [452, 460]
  2. Japan Society for the Promotion of Science (JSPS) [21245016]

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The B-12-TiO2 hybrid catalyst was effectively used for the radical reactions, such as 1,2-migrations of phenyl groups and acyl groups under irradiation by UV light, and the selectivity of the reaction was controlled by the solvent system.

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