4.7 Article

Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C-H bonds at room temperature

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 38, Pages 5731-5733

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b914736e

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Funding

  1. BASF, Inc.
  2. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R56GM063188, R01GM063188] Funding Source: NIH RePORTER

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Five-coordinate boryl complexes relevant to Ir mediated C-H borylations have been synthesized, providing a glimpse of the most fundamental step in the catalytic cycle for the first time.

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