4.7 Article

Catalytic asymmetric Strecker hydrocyanation of imines using Yb(OTf)(3)-pybox catalysts

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 34, Pages 5180-5182

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b908854g

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We have explored the highly enantioselective Strecker hydrocyanation of a wide range of aromatic, a, b-unsaturated, heterocyclic, and aliphatic aldimines with good to excellent conversions and ees up to 98% in the presence of catalytic amounts of Yb(OTf)(3)-pybox complexes.

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