4.7 Article

Recent development of reactions with alpha-diazocarbonyl compounds as nucleophiles

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 36, Pages 5350-5361

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b908378b

Keywords

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Funding

  1. NSFC [20832002, 20772003, 20821062]
  2. Ministry of Education of China, and National Basic Research Program of China [2009CB825300]

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The nucleophilic addition reaction of diazo-compound derived anions or enolates with electrophilic C=O and C=N bonds have been summarized. The subsequent reactions of the addition products demonstrate diverse reactivities of the diazocarbonyl compounds bearing other functional groups and their potential in organic synthesis. Asymmetric catalysis is also possible with diazocarbonyl compounds as nucleophiles.

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