4.7 Article

Solvent-modulated metamagnetism in a nickel(II) coordination polymer with mixed azide and carboxylate bridges

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 31, Pages 4741-4743

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b904068d

Keywords

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Funding

  1. NSFC [20571026, 20771038]
  2. MOE [NCET-05-0425]
  3. Shanghai Leading Academic Discipline Project [B409]

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A novel 2D coordination polymer consisting of ferromagnetic Ni(II) chains with alternating double EO-azide bridges and (EO-azide)bis(carboxylate) triple bridges exhibits solvent-modulated metamagnetism, and the reversible dehydration/hydration processes are accompanied by significant changes in critical temperature, critical field and hysteresis.

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