Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 34, Pages 5153-5155Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b908233f
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Funding
- DGI [CTQ2008- 00042BQU]
- Junta de Andalucia [P07-FQM-02870]
- Universidad de Huelva
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The gold complex [IPrAu(NCMe)] BF4 catalyzes the reaction of ethyl diazoacetate with benzaldehyde to give mixtures of ethyl 3-oxo-3-phenylpropanoate and ethyl 3-hydroxy-2-phenylacrylate in the first example of a group 11 metal-based catalyst for this transformation; the catalyst activity is improved by a factor of 2500 compared to those of previously reported iron-based catalysts.
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