Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 10, Pages 1216-1218Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b820879d
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Funding
- Synergy of Elements [18064006]
- Chemistry of Concerto Catalysis [20037033]
- JSPS [2075003]
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A catalytic amount of 1,2-bis(diphenylphosphino) benzene (DPPBz) achieves selective cleavage of sp(3)-carbon-halogen bond in the iron-catalysed cross-coupling between polyfluorinated arylzinc reagents and alkyl halides, which was unachievable with a stoichiometric modifier such as TMEDA; the selective iron-catalysed fluoroaromatic coupling provides easy and practical access to poly-fluorinated aromatic compounds.
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