4.7 Article

Iron-catalysed Negishi coupling of benzyl halides and phosphates

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 5, Pages 600-602

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b818961g

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Funding

  1. EPSRC [EP/D075335/1] Funding Source: UKRI
  2. Engineering and Physical Sciences Research Council [EP/D075335/1] Funding Source: researchfish

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Iron-based catalysts containing either 1,2-bis(diphenylphosphino)benzene or 1,3-bis(diphenylphosphino)propane give excellent activity and good selectivity in the Negishi coupling of aryl zinc reagents with a range of benzyl halides and phosphates.

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