Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 36, Pages 5397-5399Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b909250a
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Funding
- KRF [KRF-2008-313- C00424]
- KOSEF [R01-2009-0052888]
- CBMH
- ISTK [KK-0904-A0]
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Two metal-organic frameworks (MOFs) based on metal-organic cuboctahedra were prepared using a rigid C-3 symmetric ligand, where Zn polyhedron-based MOF (PMOF-2(Zn)) did not show any significant gas sorption behavior, whereas the isostructural Cu polyhedron-based MOF (PMOF-2(Cu)) showed a large surface area of similar to 4180 m(2) g(-1), high hydrothermal stability, and very promising H-2 sorption properties.
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