Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 41, Pages 6145-6158Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b913411e
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Funding
- National Natural Science Foundation of China [20732003]
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A series of amide-based bifunctional organocatalysts have been utilized in asymmetric reactions. Prolinamide analogues have been designed to catalyze asymmetric reactions via enamine intermediates with the assistance of tunable hydrogen bonding. In addition, the combination of various Lewis base functional groups, such as guanidine, N-oxide and phosphane, with an amide moiety have also constituted efficient bifunctional organocatalysts with unique reactivity and selectivity.
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