4.7 Article

Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 15, Pages 2035-2037

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b822942b

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Funding

  1. World Premier International Research Center (WPI) Initiative on Materials Nanoarchitectonics, MEXT, Japan
  2. Japan Synchrotron Radiation research center (JASRI) [2008B1235]

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Direct conversion of tetrahydrofurfuryl alcohol, which is one of the biomass-derived chemicals, to 1,5-pentanediol was realized by chemoselective hydrogenolysis catalyzed by Rh/SiO2 modified with ReOx species, and this reaction route gave higher yield than the conventional multi-step method.

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