4.7 Article

Discovery and early development of squaraine rotaxanes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 42, Pages 6329-6338

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b911064j

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Funding

  1. NSF
  2. NIH
  3. University of Notre Dame
  4. Direct For Mathematical & Physical Scien [0748761] Funding Source: National Science Foundation
  5. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM059078] Funding Source: NIH RePORTER

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The chemical and photophysical properties of a fluorescent squaraine dye are greatly enhanced when it is mechanically encapsulated inside a tetralactam macrocycle. This feature article describes the synthesis, structure, and photophysical performance of first-generation squaraine rotaxanes, and shows how they can be used as fluorescent imaging probes and chemosensors.

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