Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 17, Pages 2299-2301Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b818848c
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Funding
- Engineering and Physical Sciences Research Council
- GlaxoSmithKline
- Engineering and Physical Sciences Research Council [EP/E03117X/1] Funding Source: researchfish
- EPSRC [EP/E03117X/1] Funding Source: UKRI
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Heteroleptic calcium amides effect the catalytic dimerisation of the terminal alkyne CH3OCH2C CH to the hexatriene (CH3OCH2)CH=C=C=CH(CH2OCH3) under mild conditions; the reaction is proposed to occur via a dimeric calcium acetylide intermediate and to be promoted by polarisation of the electron density within the alkynide C C bonds.
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