4.7 Article

Ferrocenes with two carbohydrate appendages at the upper and lower rings are useful for investigating carbohydrate-carbohydrate interactions

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 36, Pages 5442-5444

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b910534d

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [18750103]

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The conformation of ferrocene with two beta Lac appendages is changed on addition of Ca2+ and Na+, which can be ascribed to intramolecular beta Lac-beta Lac interactions mediated by these cations and the resultant stabilization of twisted rotamers along the Cp-Fe-Cp axis.

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