4.7 Article

Coordination chemistry approach to the long-standing challenge of stereocontrolled chemical glycosylation

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 42, Pages 6379-6381

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b903942b

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Funding

  1. National Science Foundation [CHE-0547566]
  2. American Heart Association [0855743G]
  3. Deutsche Forschungsgemeinschaft

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This study clearly demonstrates that a multi-dentate metal coordination to the leaving group, along with O-5 and/or a protecting group at O-6, has a strong effect on the stereo-selectivity of chemical glycosylation.

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