4.7 Article

Regioselective copper-catalyzed chlorination and bromination of arenes with O-2 as the oxidant

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 42, Pages 6460-6462

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b915487f

Keywords

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Funding

  1. Department of Energy [DE-FG02-05ER15690]
  2. China Scholarship Council

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Electron-rich aromatic C-H bonds undergo regioselective chlorination and bromination in the presence of CuX2, LiX (X = Cl, Br) and molecular oxygen. Preliminary mechanistic insights suggest that the bromination and chlorination reactions proceed by different pathways.

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