4.7 Article

Highly oxidized diiron complexes: generation, spectroscopy, and stabilities

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 19, Pages 2637-2639

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b903500a

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Funding

  1. NCRR NIH HHS [5P41RR001209] Funding Source: Medline
  2. NATIONAL CENTER FOR RESEARCH RESOURCES [P41RR001209] Funding Source: NIH RePORTER

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Oxidation of the diferric complex [(LFeOFeL)-O-III-L-III] to the monoradical complex [(LFeOFeL center dot)-O-III-L-III](+) and the diradical complex [(LFeOFeL center dot)-Fe-center dot-O-III-L-III](2+) is followed by a decay into monomeric complexes including a highly reactive putative [LFeIV=O] complex.

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