4.7 Article

First expeditious synthesis of 6,11-diamino-[6]carbohelicenes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 32, Pages 4827-4828

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b905670j

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The first synthesis of 6,11-diamino-[6]carbohelicenes is described: the short 5 step sequence involves Suzuki-Miyaura coupling, functional group transformations and electrophilic aromatic cyclisation; the original strategy allows the preparation of di- and tetra-substituted helicenes in comfortable yields.

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