4.7 Article

Enantioselective self-assembly of chiral calix[4]arene acid with amines

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 9, Pages 1121-1123

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b817974c

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Funding

  1. National Natural Science Foundation of China [20872040]
  2. Scientific Research Projects of Education Department of Guangxi Province [2006]

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A chiral calix[4] arene bearing L-2,3-dibenzoyltartaric acid groups at the lower rim was synthesized and could enantioselectively self-assemble to result in a gel or suspension only with one enantiomer of chiral amines; as revealed by electron microscopy, the resultant gel was of nanofibers with a high aspect ratio but the suspension was composed of nanospheres.

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