4.7 Article

Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic beta-hydroxy carbonyls

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 43, Pages 6577-6579

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b914207j

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Funding

  1. Korea Science and Engineering Foundation (KOSEF)
  2. Korea government (MEST) [R01-2008-000-20332-0]

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The highly enantioselective conjugate boration of six-membered and seven-membered cyclic enones and unsaturated esters was achieved by the use of a copper-(R,S)-Taniaphos complex with up to 99% cc under optimal conditions.

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