4.7 Article

Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: asymmetric entry to the spiro-beta-lactam core of chartellines

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 41, Pages 6264-6266

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b913770j

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan

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A versatile, highly enantiocontrolled entry to the spiro-beta-lactam core of chartellines has been developed by expanding the scope of oxidative nitrogen atom transfer methodology based on chiral Rh-nitrenoid species.

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