4.7 Article

Synthesis and structural characterisation of stable cationic gold(I) alkene complexes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 26, Pages 3877-3879

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b908109g

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Treatment of [AuCl(PBu3t)] with AgSbF6 in CH2Cl2 at room temperature in the presence of the alkenes norbornene, norbornadiene, trans-cyclooctene, and also interestingly, isobutylene, leads to the formation of stable crystalline complexes [Au(PBu3t)(alkene)][SbF6], characterised by NMR spectroscopy and X-ray crystallography.

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