4.7 Article

Experimental realization of catalytic CH4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 22, Pages 3270-3272

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b823303a

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Funding

  1. Chevron Energy Technology Company and Scripps Florida

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A discrete, air, protic, and thermally stable (NNC) Ir(III) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO4 and KIO3 gives the oxy-ester.

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