Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 31, Pages 4720-4722Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b907908d
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Funding
- CNRS
- ANR [ANR-08-BLAN-0137-01]
- Agence Nationale de la Recherche (ANR) [ANR-08-BLAN-0137] Funding Source: Agence Nationale de la Recherche (ANR)
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The 4-hydroxyimidazolium salt, readily prepared in two steps by acylation of a formamidine and quaternization of the second nitrogen, affords, after deprotonation, the anionic imidazol-2-ylidene-4-olate, which can be complexed to a transition metal and still be subsequently functionalized at O or C backbone atom in the outer coordination sphere of the metal.
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