4.7 Article

Bridgehead enolates and bridgehead alkenes in a welwistatin model series

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 11, Pages 1398-1400

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b820674k

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Bridgehead metallation is possible in a ketone having the welwistatin skeleton, and this facilitates installation of the isothiocyanate function present in the natural product, and also enables synthesis of remarkable bridgehead alkenes.

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