Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 2, Pages 206-208Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b816742g
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Funding
- NIH [2 S06 GM063119-05]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [S06GM063119] Funding Source: NIH RePORTER
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Three Co(II) isomers assembled from D-, or L-, or DL-camphorate together with achiral isonicotinate exhibit a clear relationship between chirality and helicity even though chiral molecules are not in the backbone of the helix: the absolute sense of helix made of achiral components is controlled by chains of metal and enantiopure chiral ligands running perpendicular to helix in two enantiomeric forms.
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