4.7 Article

Two are not always better than one: ligand optimisation for long-living light-emitting electrochemical cells

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 15, Pages 2029-2031

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b821602a

Keywords

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Funding

  1. European Union (Heteromolmat, STRP 516982)
  2. ESF [Eurocores-05SONS-FP-021]
  3. Spanish Ministry of Science and Innovation (MICINN) [MAT2006-28185-E, MAT2007-61584, CSD2007-00010, CTQ2006-14987-C02-02]
  4. Generalitat Valenciana
  5. European FEDER funds
  6. Swiss National Science Foundation
  7. University of Basel
  8. Swiss Nanoscience Institute
  9. Swiss National Center of Competence in Research Nanoscale Science''
  10. the Program Ramon y Cajal''
  11. FPU

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The complex [Ir(ppy)(2)(dpbpy)][PF6] (Hppy = 2-phenylpyridine, dpbpy = 6,6'-diphenyl-2,2'-bipyridine) has been prepared and evaluated as an electroluminescent component for light-emitting electrochemical cells (LECs); the complex exhibits two intramolecular face-to-face pi-stacking interactions and long-lived LECs have been constructed; the device characteristics are not significantly improved in comparison to analogous LECs with 6-phenyl-2,2'-bipyridine.

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