4.7 Article

Reactions of Ar ' CrCrAr ' with N2O or N-3(1-Ad): complete cleavage of the Cr-Cr quintuple interaction

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 17, Pages 2332-2334

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b901494b

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Funding

  1. National Science Foundation [CHE-0641020]

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Reaction of Ar'CrCrAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pr-2(i))(2)) with heterocumulene reagents N2O or N-3(1-Ad) resulted in Ar'Cr(mu-O)(2)Cr(O)Ar' or Ar'Cr(mu(2):eta(1),eta(3)-N-3(1-Ad))CrAr' which have no metal-metal bonding.

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