4.7 Article

Photolysis of diarylvinylcyclopropenes for the construction of 1-methylene-8a-aryl-1,8a-dihydroazulene skeletons

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 11, Pages 1392-1394

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b820212e

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Funding

  1. Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
  2. National Basic Research Program of China [2009CB825300]
  3. National Natural Science Foundation of China [20872162, 20672127, 20732008]

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Photoirradiation of vinylcyclopropenes 1 in a Pyrex tube provides 1-isopropylidene-3,8a-diphenyl-1,8a-dihydroazulene derivatives 2 in moderate to good yields within 4.5-14 h. A plausible mechanism has been discussed for the formation of these interesting products.

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