4.7 Article

Selective oxidation of propylamine to propionitrile and propionaldehyde on oxygen-covered gold

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 7, Pages 761-763

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b821050k

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Funding

  1. Department of Energy [DE-FG02-04ER15587]
  2. Welch Foundation [F-1436]
  3. National Science Foundation [CTS-0553243]

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Oxidative dehydrogenation of amines using heterogeneous gold catalysts has unanticipated potential; chemisorbed atomic oxygen is used to activate propylamine, producing propionitrile and/or propionaldehyde on a single-crystal Au(111) surface.

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