4.7 Article

Photocontrolled nucleobase binding to an organometallic RuII arene complex

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 43, Pages 6622-6624

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b914153g

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Funding

  1. WPRS/ORSAS (UK)
  2. CONACyT (Mexico)
  3. Marie Curie Intra European Fellowship [220281]
  4. EDRF
  5. AWM

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The complex [(p-cym)Ru(bpm)(py)][PF6](2) (where p-cym = para-cymene, bpm = 2,2'-bipyrimidine and py = pyridine) is the first ruthenium(II) arene complex that can selectively photodissociate a monodentate ligand (py) when excited with visible light and form a reactive aqua derivative able to bind to a DNA base.

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