4.7 Article

The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(II) or low-spin Fe(0)?

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 30, Pages 3555-3557

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b805262j

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Funding

  1. Biotechnology and Biological Sciences Research Council Funding Source: Medline

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Infrared data for mono-iron complexes possessing two cis-CO together with Mossbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).

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