4.7 Article

Cooperativity between pi-pi and H-bonding interactions-a supramolecular complex formed by C-60 and exTTF

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 45, Pages 5993-5995

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b811358k

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Funding

  1. MEC of Spain [CTQ2005-02609/BTQ, CSD2007-0010]
  2. Comunidad de Madrid [P-PPQ-000225-0505]
  3. Deutsche Forschungsgemeinschaft [SFB 583]
  4. FCI
  5. Office of Basic Energy Sciences of the US Department of Energy

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A highly stable supramolecular complex from C-60 and exTTF (K-a approximate to 10(6) M-1) has been achieved by means of pi-pi and H-bonding interactions; experimental evidence reveals the formation of a radical-ion pair (tau = 9.3 ps) upon photoexcitation.

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