Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 36, Pages 4360-4362Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b807640e
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- M.I.U.R. (Rome)
- University of Bologna
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Remarkable generality in scope of new C9-benzoylcupreines bearing electron-withdrawing substituents for the nitroaldol condensation with fluoromethyl ketones is presented. Both tri- and difluoromethyl ketones provided excellent levels of stereo-induction (ee 76-99%) under mild reaction conditions and low loading of catalyst (1-5 mol%).
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