4.7 Article

Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 41, Pages 5224-5226

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b809433k

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan

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Three-component coupling of bis(dialkylamino)chloroborane, alkynes and organozirconium reagents proceeded in the presence of palladium catalysts, leading to the formation of stereo-defined alkenylborane derivatives via cis-carboboration of carbon-carbon triple bonds.

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