Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 6, Pages 753-755Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b715633b
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A heteroditopic receptor having crown ether and trifluoroacetylcarboxanilide groups selectively recognizes both potassium and cyanide ions in acetonitrile with an association constant of as high as K-a = 1.9 x 6 10(7) M-1 through a highly cooperative ion-pair interaction, resulting in two orders of magnitude enhancement in the binding affinity.
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