4.7 Article

The mechanism of carbonate formation on Pd-Al2O3 catalysts{

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 3, Pages 320-322

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b713161e

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Vibrational spectroscopic investigations of the adsorption of isotopically labelled and unlabelled CO and CO2 reveal that carbonate formation on Pd-alumina catalysts occurs via an oxygen down'' reaction of CO with hydroxyl groups on the support, whereas CO dissociation on Pd can be excluded.

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