4.7 Article

Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 35, Pages 4135-4137

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b805785k

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Funding

  1. Korea Research Foundation [KRF-2006-352-D00040]
  2. US Department of Energy [DEFG02-1ER15244]

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Separation of CO2/CH4 mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (similar to 17) are obtained, especially in the material with open metal sites.

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