4.7 Article

O-Dihaloarenes as aryne precursors for nickel-catalyzed [2+2+2]cycloaddition with alkynes and nitriles

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 26, Pages 2992-2994

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b801870g

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o-Dihaloarenes acting as aryne precursors react with acetylenes and nitriles catalyzed by the NiBr2(dppe)/dppe/Zn system to give substituted naphthalene, phenanthridine or triphenylene derivatives depending on the reaction conditions in moderate to excellent yields with good tolerance of functional groups.

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