4.7 Article

Phosphoesterase activity of polyoxomolybdates: diffusion ordered NMR spectroscopy as a tool for obtaining insights into the reactivity of polyoxometalate clusters

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 24, Pages 2774-2776

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b802671h

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Diffusion ordered NMR spectroscopy (DOSY NMR) is shown to be an excellent tool for observing reactive transients in the hydrolysis of the phosphatase model substrate (p-nitrophenyl)phosphate (NPP) promoted by polyoxomolybdate.

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