4.7 Article

Ni(II)-catalyzed enantioselective Nazarov cyclizations

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 36, Pages 4315-4317

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b806870d

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Funding

  1. Swiss National Science Foundation

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Nazarov cyclizations are catalyzed by a dicationic Ni(II) complex containing the chiral tridentate phosphine Pigiphos; the catalyst exerts a high degree of torquoselectivity and affords the products in up to 88% ee.

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