4.7 Article

Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 39, Pages 4780-4782

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b808374f

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Funding

  1. Overseas Research Students Awards Scheme (Universities UK)
  2. Engineering and Physical Sciences Research Council (UK)
  3. Cambridge Overseas Trust
  4. VESKI
  5. CSIRO
  6. Materials World Network (NSF/ARC)

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A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride-mediated process in scCO(2) has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.

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