4.7 Article

Alkynes as masked ylides: Gold-catalysed intermolecular reactions of propargylic carboxylates with sulfides

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 2, Pages 238-240

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b714813e

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Funding

  1. EPSRC [EP/E032168/1] Funding Source: UKRI
  2. Engineering and Physical Sciences Research Council [EP/E032168/1] Funding Source: researchfish

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The in situ-generation of sulfur ylides by the gold-catalysed rearrangement of propargylic carboxylates in the presence of sulfides has resulted in highly efficient and novel transformations.

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