Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 2, Pages 193-195Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b711786h
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A diastereoselective procedure to obtain N-para-methoxybenzyl bis-alpha,alpha'-3-(3-phenyl-2-pyrrolidinone)yl substituted ketones with non-adjacent quaternary stereocenters, DL-2 and meso-3 was followed by a photoinduced, spin-dependent, and diastereoselective decarbonylation to give compounds DL-4 and meso-5, with adjacent all-carbon quaternary stereogenic centers.
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